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Q.

In the reaction; As2S3+HNO3H3AsO4+H2SO4+NO the element(s) oxidized is/are:

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a

As only

b

N only

c

S only

d

As and S both

answer is D.

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Detailed Solution

As2​S3​ + HNO3​ → H3​AsO4​ + H2​SO4​ + NO

+3  -2         +5           +5           +6          +2
                            (oxidation) (oxidation)(reduction)
Hence, the elements oxidized are both As and S.

As3+As5++2e-S2S6++8e-

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