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Q.

In the reaction C2H4x Product, if the hybridization of carbon atom (s) in the product is sp3,X is not

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a

HCl/AlCl3

b

O3/Zn+H2O

c

 Br2/CCl4

d

H2/Ni

answer is C.

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Detailed Solution

In the given reaction C2H4 ⟶ X Product, the determination of hybridization depends on the type of reaction and the product formed. The key factor to consider is the reagents used. When ozone (O3) followed by zinc and water (Zn + H2O) is employed, the process known as ozonolysis occurs. In this reaction, the alkene, C2H4, is broken into smaller compounds, specifically aldehydes or ketones. Both of these products have carbon atoms that remain sp2 hybridized.

In contrast, other reactions typically lead to products in which the carbon atoms become sp3 hybridized. For example, hydrogenation of C2H4 or reactions involving halogens can convert the initial double-bonded carbons into single-bonded (sigma bond) carbons, resulting in sp3 hybridization.

Thus, to answer the question, when the product has sp3 hybridization, X could be any reagent except O3/Zn + H2O, as ozonolysis does not yield sp3 hybridized carbons. Instead, it produces aldehydes or ketones with sp2 hybridized carbon atoms. This reaction highlights a specific instance where the original alkene’s hybridization shifts from sp2 to sp3 (except in the case of ozonolysis).

In summary, the reagents O3/Zn + H2O do not lead to sp3 hybridization in the product, making X a unique case. This distinction is crucial for understanding C2H4 hybridization and how it changes under different chemical conditions.

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