Q.

In the redox reaction,  2KMnO4+3H2SO4+5H2C2O4K2SO4+2MnSO4+10CO2+8H2O

the volume of 0.1M KMnO4 required to oxidize 25ml of 0.25M H2C2O4 solution is.

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a

1.2. lit

b

25 lit

c

125ml

d

25ml

answer is C.

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Detailed Solution

The provided reaction is:

5H2C2O4+2KMnO4+3H2SO42MnSO4+K2SO4+10CO2+8H2O 

According to the molarity equation


M1V1n1KMnO4=M2V2n2oxalic acid 


or 0.1×V12=0.25×255

V1=2×0.25×255×0.1=12.50.5 

V1=25ml

Hence, option(c) is the answer.

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