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Q.

In the scheme given below, X and Y , respectively, are

 Metal halide  aq. NaOH White precipitate (P) + Filtrate (Q) P heat  aq. H2SO4 PbO2 (excess)  X( a coloured species in soloution) QWarmMnO(OH)2 Conc. H2SO4Y (gives blue -coloration with KI-starch paper)

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a

CrO42 and Br2

b

MnO42 and Cl2

c

MnSO4 and HOCl

d

MnO4 and Cl2

answer is C.

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Detailed Solution

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Metal halide is MnCl2
MnCl2+NaOH Mn(OH)2+2NaCl                                (P)                 (Q)
2MnOH2+5H2SO4+PbO2 PbSO4+2HMnO4+4H2O       (P)                                                                 (X)2NaCl+2H2SO4+MnO(OH)2warmCl2+Na2SO4+MnSO4+3H2O   (Q)                                                       (Y) 

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In the scheme given below, X and Y , respectively, are Metal halide → aq. NaOH White precipitate (P) + Filtrate (Q) P→ heat  aq. H2SO4,  PbO2 (excess)  X( a coloured species in soloution) Q→WarmMnO(OH)2 Conc. H2SO4Y (gives blue -coloration with KI-starch paper)