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Q.

In the Solvay process the following reactions takes place
i) 2NH3+H2O+CO2(W)
ii) (W)+H2O+CO2(X)
iii) (X)+NaClM+N
iv) (M)ΔP(S)+Q(v)+R(g)

Which of the following statement(s) is /are correct.

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a

On adding phenolphthalein indicator to (M) there is no colour change.

b

M is sparingly soluble in water due to polymeric hydrogen bonding

c

Compound (W) is more basic than M.

d

Aqueous solution of P is less basic than (W) or (X) or (M)

answer is A, C.

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Detailed Solution

i) 2NH3 + H2O + CO2 → (NH4)2CO3 (W)

ii) (NH4)2CO3 + H2O + CO2 → 2NH4HCO3 (X)

iii) NH4HCO3 + NaCl → NaHCO3 (M) + NH4Cl (N)

iv) 2NaHCO3 (M) → 2Na2CO3 (s) (P) + H2O (v) (Q) + CO2 (g) (R)

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In the Solvay process the following reactions takes placei) 2NH3+H2O+CO2→(W)ii) (W)+H2O+CO2→(X)iii) (X)+NaCl→M+Niv) (M)⟶ΔP(S)+Q(v)+R(g)Which of the following statement(s) is /are correct.