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Q.

In the species O2,O2+,O2and O22, the correct decreasing order of bond strength is given as

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a

O22>O2>O2+>O2

b

O2+>O2>O2>O22

c

O2>O2+>O2>O22

d

O2>O22>O2>O2+

answer is B.

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Detailed Solution

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The formula for calculating bond order:

  • B.O.=NBNA2
  • The number of electrons in the antibonding and bonding molecular orbitals, respectively, is NA, NB.

Calculating bond order of given species:

  • B.O for O2=1/2×[10–6]; B.O for O2=2
  • B.O for O2-=1/2×[10–7]; B.O for O2-=1.5
  • B.O for O2+=1/2×[10–5]; B.O for O2+=2.5
  • B.O for O22=1/2×[10–8]; B.O for O22=1

Arranging in increasing order of bond lengthO2+>O2>O2>O22

 

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