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Q.

In the spectrum of hydrogen, the ratio of the longest wavelength in the Lyman series to the longest wavelength in the Balmer series is

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a

275

b

527

c

49

d

94

answer is B.

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Detailed Solution

The wavelength of a spectral line in the Lyman series  is

1λL=R112-1n2,n=2,3,4,

and that in the Balmer series is 

1λB=R122-1n2,n=3,4,5

 For the longest wavelength in the Lyman series, n=2

  1λL=R112-122=R11-14=R4-14=3R4

 or λL=43R

For the longest wavelength in the Balmer series, n = 3

  1λB=R122-132=R14-19=R9-436=5R36

 or λB=365R

 Thus, λLλB=43R365R=43R×5R36=527

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