Q.

In the titration of sodium thiosulphate and iodine, the equivalent mass of the former is equal to

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a

molar mass/2

b

molar mass/4

c

molar mass/3

d

molar mass

answer is A.

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Detailed Solution

 

The equivalent weight is the gram molecular weight divided by the number of electrons lost or gained by each molecule.

The reaction is 2S2O32+I2S4O62+2I Equivalent mass= Molar mass

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