Q.

In the van der Waal's equation for real gases, corrections are introduced for both the pressure and the volume terms of the Ideal Gas Equation. Identify the origin of both correction factors and specify whether each is added to or subtracted from the corresponding term.

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a

PressureVolume
attractive forces / addedmolecular size / substracted

b

PressureVolume
attractive forces / subtractedmolecular size / added

c

PressureVolume
molecular size / substractedattractive forces / added

d

PressureVolume
molecular size / addedattractive forces / subtracted

answer is B.

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Detailed Solution

In the van der Waal's equation for real gases, corrections are introduced for both the pressure and the volume terms of the Ideal Gas Equation. Identify the origin of both correction factors and specify whether each is added to or subtracted from the corresponding term. P+aVm2Vmb=RT 

PressureVolume
attractive forces / addedmolecular size / substracted
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In the van der Waal's equation for real gases, corrections are introduced for both the pressure and the volume terms of the Ideal Gas Equation. Identify the origin of both correction factors and specify whether each is added to or subtracted from the corresponding term.