Q.

In what ratio amounts of H2SO4 and H3PO4 react with the same amounts of NaOH to form normal salts?

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a

1 : 1

b

3 : 2

c

2 : 3

d

1 : 3

answer is B.

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Detailed Solution

H2SO4+2NaOHNa2SO4+2H2O

 moles of H2SO4 required for 1mol of NaOH=12=0.5 H3PO4+3NaOHNa3PO4+3H2O  moles of H3PO4 required for 1mol of NaOH=13  Hence, mass of H2SO4: mass of H3PO4=12:13 =3:2MH2SO4=MH3PO4=98

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