Q.

In what volume of 0.02M of HCl aqueous solution should be added to 0.02M of imidazole aqueousolution (base ionization constant =9.8×10-8 at 250C) to make 100ml of a buffer with (pH=7). (log 9.8=0.9912) and (log(1.019)=0.008)

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a

33mL

b

74mL

c

26mL

d

67ML

answer is B.

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Detailed Solution

pKb=-log Kb=-log 9.8×10-8

=8-log9.8=(8-0.9912)=7.0088

For basic buffer solution

POH=pKb-log (Wb)(salt)

(14-7)=7.008-log 0.02×V1-V2V2×0.02

log V1-V2V2=0.008 V1-V2V2=1.019(1) V1+V2=100(2) V2=33mL V1=67 mL     

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