Q.

In which case is the number of molecules of water maximum

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a

10-3 mol of water

b

0.18 g of water

c

18 mL of water

d

0.00224 L of water vapours at 1 atm and 273 K

answer is A.

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Detailed Solution

(a) 18 mL water
As dH2O=1g/mL  So WH2O=18g
                                   nH2O=1818=1
                                   molecules = 1x NA
(b) 0.18g of water 
nH2O=0.1818=0.01
 (molecules) H2O=0.01×NA
 (c) VH2O(g)STP=0.00224L
nH2O=V22.4=0.0022422.4=0.0001
Molecules = 0.0001 x NA
(d) nH2O = 10-3  (molecules)H2O = 10-3 x NA

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