Q.

In which case pH will not change on dilution

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a

0.01 M NaH2PO4

b

0.01 M CH3COONH4 

c

0.01 M CH3COONa + 0.01  M CH3COOH  buffer

d

in all cases

answer is D.

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Detailed Solution

Mixture of sodium acetate and acetic acid is a buffer of pH value equal to pKa so its buffer capacity is very high and hence its pH will not change significantly while CH3COONH4 is a salt of weak acid CH3COOH and weak base NH4OH whose magnitude of Ka and Kb are equal. So its pH does not depend upon concentration. Furthermore, NaH4PO4 is, in fact, a single solute buffer.

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In which case pH will not change on dilution