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In which of following option the (X-A-X) adjacent angle difference in cationic part and anionic part is maximum in the solid state?

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By Expert Faculty of Sri Chaitanya
a
PCl5
b
Cl2O6
c
N2O5
d
BeH2
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detailed solution

Correct option is C

The N is having sp hybridized with the two bound pairs and the cation of the N2O5 is NO2+. Similar to this, the N2O5anion is NO3, with the N having hybridized with the three bound pairs.
Thus, the N2O5 cation is NO2+ and the N2O5 anion is NO3, and the N atom in the cation has hybridised due to the two bound pairs in the sp state.

N2O5NO2+180+NO3120


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