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In which of following there exists a $p π - d π$ bonding

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Diamond

Graphite

Dimethyl amine

Trisilylamine

answer is D.

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Detailed Solution

Trisilylamine, N(SiH₃)₃ has a planar structure where N is sp²-hybridized and there is a π-π overlapping (side wise) due to the filled unhybridized p-orbital of N and empty d- orbitals of Si atoms.

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