Q.

In which of the following all the given characteristics are present ?

  • Vacant orbitals involved in hybridization
  • Octet of underlined atom is completed
  • Geometry of underlined atom is tetrahedral

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a

B_2H6

b

Si2H6

c

I2Cl6

d

Al2Cl6

answer is C.

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Detailed Solution

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Low melting and boiling points are characteristics of aluminum chloride. 180 C is the temperature at which it sublimes . Al2Cl6 is a poor conductor of electricity when it is molten. Aluminum chloride is typically white in color but turns yellow when it comes into contact with iron trichloride.

Vacant orbitals in Al2Cl6 participate in hybridization. The underlined atom's octet is full in Al2Cl6 , while its geometry is tetrahedral in Al2Cl6 . The answer that is correct is therefore (c).

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