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Q.

In which of the following cells net cell reaction is: 

Ag+(aq)+Cl(aq)AgCl(s)

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a

Ag|AgCl(s)|KCl(aq)|Ag

b

Ag|AgNO3||NH4NO3||KCl(aq)|AgCl|Ag

c

All of the above 

d

Ag|AgCl(s)|KCl(aq)||NH4NO3||AgNO3|Ag

answer is A.

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Detailed Solution

Ag|AgCl(s)|KCl(aq)||NH4NO3||AgNO3|Ag

          Salt bridge 

LHE reaction: Ag+ClAgCl(s)+e- 

RHE reaction: Ag++e-Ag

Net reaction: Ag++ClAgCl(s)

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