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In which of the following changes there is no change in hybridisation of the central atom?

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${PCl}_{5} + {Cl}^{-} ⟶ {PCl}_{6}^{-}$

${NH}_{3} + H^{+} ⟶ {NH}_{4}^{+}$

${BF}_{3} + F^{-} ⟶ {BF}_{4}^{-}$

$C_{2} H_{4} \overset{H_{2} / Ni}{\to} C_{2} H_{6}$

answer is D.

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Detailed Solution

${NH}_{3} + H^{+} ⟶ {NH}_{4}^{+}$

Ammonia has a pyramidal shape in which N has sp³ hybridization. In the Ammonium ion, the shape of ion is tetrahedral and N has sp³ hybridization.

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