Q.

In which of the following compound(s) the  CCl bond is shorter than that in  C2H5Cl?

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a

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b

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c

CH2=CHCl

d

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answer is A, B, D.

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Detailed Solution

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When Cl  is directly attached to benzene, +R effect of chlorine is observed.  Which increases the bond order of  CCl bond.

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