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Q.

In which of the following compound/ions the dπpπ is not present?

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a

HPO32

b

SO2

c

NO2+

d

N3

answer is A, B.

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Detailed Solution

N cannot form dπpπ bond with N or O.

So, the hybridization of the central atom of N3

In NO2+, the nitrogen atom is bonded to one oxygen by the double bond while to the other oxygen atom by the coordinate covalent bond.

Hence, the correct option is (a, b).
 

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