Q.

In which of the following compounds delocalisation is not possible

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a

1,4-pentadiene

b

1,3-butadiene

c

1,3,5-hexatriene

d

benzene

answer is A.

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Detailed Solution

1) H2C ═ CH – CH2 – HC ═ CH2

Resonance is not possible [delocalisation of π-electrons] Since the π-bonds are isolated and they are non conjugated.

2) Question Image

Resonance [delocalisation of π e-s] is possible, since it is a conjugated system.

Question Image

Resonance [delocalisation of π e-s] is possible, since it is also a conjugated system.

Question Image

Resonance is possible, since it is also a conjugated system.

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