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In which of the following equilibrium systems is the rate of the backward reaction favoured by increase of pressure

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${PCl}_{5} ⇌ {PCl}_{3} + {Cl}_{2}$

$2 {SO}_{2} + O_{2} ⇌ 2 {SO}_{3}$

$N_{2} + 3 H_{2} ⇌ 2 {NH}_{3}$

$N_{2} + O_{2} ⇌ 2 NO$

answer is A.

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Detailed Solution

The rate of backward reactions favoured by increase of pressure in the reaction as $∆ n$ is positive

${PCl}_{5} ⇌ {PCl}_{3} + {Cl}_{2}$

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