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Q.

In which of the following homolytic bond fission takes place?

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a

Free radical chlorination of methane

b

Addition of HBr to double bond

c

Alkaline hydrolysis of ethyl chloride

d

Nitration of Benzene

answer is A.

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Detailed Solution

CH4+Cl2 heat  or light   CH3Cl

When an alkane is treated with a halogen (Cl2 or Br2) in the presence of heat or light, a mixture of mono and polyhaloalkanes is formed by successive halogenation.

 

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In which of the following homolytic bond fission takes place?