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In which of the following homolytic bond fission takes place?

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Free radical chlorination of methane

Addition of HBr to double bond

Alkaline hydrolysis of ethyl chloride

Nitration of Benzene

answer is A.

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Detailed Solution

${CH}_{4} + {Cl}_{2} \underset{or light}{\overset{heat}{⟶}} C H_{3} C l$

When an alkane is treated with a halogen (Cl₂ or Br₂) in the presence of heat or light, a mixture of mono and polyhaloalkanes is formed by successive halogenation.

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