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Q.

In which of the following is /are contains ionic, covalent bond and dative bonds are present 

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a

NH4Cl

b

CuSO4,5H2O

c

CaC2

d

NaCl

answer is A, B.

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Detailed Solution

Coordinate bond or dative bond is the bond between the bonded atoms where the electron pairs belong to one of the bonded atoms.
CuSO4​⋅5H2​O exists as [Cu(H2O)4]2+SO42-.H2O, where there is dative bond between water molecule and Cu of [Cu(H2​O)4​]2+ complex. There is an ionic bond between the coordination sphere and SO42-. 

In NH4Cl, there are three covalent bond between one N atom and 3 hydrogen atoms, one dative bond between one N atom and one H atom. Also, there is one ionic bond between NH4+ and Cl-.

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