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Q.

In which of the following metal carbonyls, the C-O bond length is minimum?

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a

Mn(CO)6+

b

Cr(CO)6

c

Ti(CO)62

d

V(CO)6

answer is B.

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Detailed Solution

As charge on C.A. ,CO  bond strength 

or C-O bond order  thus, C-O bond length 

In Mn(CO)6+ C-O bond length is minimum as the bond order is maximum in this molecule  among all.

Hence correct option B.

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