Q.

In which of the following molecules / ions, all the bonds are not of equal length.

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a

SiF4

b

SF4

c

XeF4

d

XeO64-

answer is B.

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Detailed Solution

Question Image

(1) Hybridization : sp3 

Shape:Regular tetrahedron 

All SiF bonds are of equal length.

Question Image

(2) Hybridization : sp3d

Shape : See-saw Axial 

SF bond is longer than equatorial SF bond.

Question Image

(3) Hybridization : sp3d2

Shape : Square planar Axial 

XeF bonds are of equal length.

Question Image

(4)  Hybridization : sp3 

Shape:Regular tetrahedron 

All B-H bonds are of equal length.

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