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Q.

In which of the following octahedral comple-xes of cobalt (atomic number = 27) will the magnitude of 0be the highest?

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a

[Co(C2O4)3]3–

b

[Co(H2O)6]3+

c

[Co(NH3)6]3+

d

[Co(CN)6]3–

answer is D.

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Detailed Solution

Δ0​ depends upon ligands because they cause large crystal field splitting depending upon their position in spectrochemical series i.e CN  > NH3 > H2​O > C2​O42−​
Greater the donating nature of ligand greater will be the ligand strength and therefore higher will the CFSE in octahedral complex

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