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Q.

In which of the following order the given complex ions are arranged correctly with respect to their decreasing spin only magnetic moment?

i) FeF63                

ii) Co(NH3)63+

iii) NiCl42

iv) Cu(NH3)42+

 

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a

ii > iii > i > iv 

b

i > iii > iv > ii

c

iii > iv > ii > i

d

ii > i > iii > iv

answer is B.

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Detailed Solution

FeF63-Fe+3=3 d5n=5CoNH36+3-Co+3=3 d6n=0NiCl4+2-  Ni=+2  3 d8n=2CuNH34+2-Cu+2  3 d9n=1

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