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Q.

In which of the following order the given complex ions are arranged correctly with respect to their decreasing spin only magnetic moment?
i) [FeF6]3– 

ii) [Co(NH3)6]3+

iii) [NiCl4]2– 

iv) [Cu(NH3)4]2+

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a

 ii > i > iii > iv

b

 i > iii > iv > ii

c

 iii > iv > ii > i

d

 ii > iii > i > iv 
 

answer is B.

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Detailed Solution

  • FeF63- In this Flourine  act as weak field ligand thus electronic configuration is t2g3eg2; number of unpaired electron is 5.[Co(NH3)6]3+  t2g6eg0has No unpaired electron that shows NH3 is strong field light which causes pairing, number of unpaired electron is zero.[NiCl4]2- ;Ni2+ 3d8 has 2 unpaired electrons.

[Cu(NH3)4]2+: Cu2+ 3d9 has 1 unpaired electrons. Higher the number unpaired electron higher is the spin only magnetic moment.

Hence, correct option is: (B) i > iii > iv > ii

 

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