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Q.

In which of the following - bonding is possible ?

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a

NO3-

b

CO32-

c

NO2-

d

PO43-

answer is B.

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Detailed Solution

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In P=O bond, π - bond is formed by the sidewise overlapping of d - orbital of P and p - orbital of oxygen. Hence, it is formed by pπ and dπ overlapping.

In nitrogen and carbon, no vacant d-orbital is present. So, they do not form pπ−dπ bond.

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