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Q.

In which of the following pairs of molecules/ions both the species are not likely to exist?

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a

H2+ ,  He22

b

H2,He22

c

H22+,He2

d

H2,He22+

answer is C.

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Detailed Solution

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H22+ =  σ1s0 σ1s0   
Bond order for 12 =  12 ( 0 – 0 ) = 0
  He2=  σ1s2 σ1s2     
Bond order for He2 =  12 ( 2 – 2 ) = 0
so both H22+  and  He2 do not exist 
 

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