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In which of the following reaction of aniline, the benzene nucleus of aniline is not attacked by the reagent

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reaction with bromine water

reaction with acetyl chloride in presence of pyridine

reaction with conc. Sulphuric acid at 453K

reaction with nitration mixture

answer is B.

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Detailed Solution

$Ph - {NH}_{2} + {CH}_{3} COCl \overset{Pyridine}{\to} Ph - {NHCOCH}_{3} + HCl$

it is an example of N- acylation

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