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Q.

In which of the following reactions, anti Markownikoff's rule is observed?

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a

${CH}_{3} - CH = {CH}_{2} + HI \overset{peroxide}{\to}$

b

${CH}_{3} - CH = {CH}_{2} + HBr \overset{peroxide}{\to}$

c

${CH}_{3} - C = {CH}_{2} + H_{2} {SO}_{4} \to$

d

${CH}_{3} - CH = {CH}_{2} + HCl \overset{peroxide}{\to}$

answer is B.

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Detailed Solution

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Anti Markownikoff's rule:- When an unsymmetrical alkene is treated with an unsymmetrical reagent (HX), in the presence of peroxide, the negative part of the reagent (−X) gets added to the unsaturated carbon of the double bond which contains more number of hydrogen atoms.
Here HBr in presence of peroxide gets added to unsymmetrical alkene according to Anti-Markownikoff's rule. ${CH}_{3} - CH = {CH}_{2} + HBr \overset{peroxide}{\to} {CH}_{3} - {CH}_{2} - {CH}_{2} Br$

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