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Q.

In which of the following reactions aromatic aldehyde is treated with acid anhydride in presence of corresponding salt of the acid to give unsaturated aromatic acid

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a

Friedel-Crafts reaction

b

Perkin reaction

c

Wurtz reaction

d

None of these

answer is B.

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Detailed Solution

The Perkin reaction gives an alpha, beta-unsaturated aromatic acid via the aldol condensation of an aromatic aldehyde and an acid anhydride. The alkali salt of the acid is also present. This alkali salt acts as a base catalyst.

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In which of the following reactions aromatic aldehyde is treated with acid anhydride in presence of corresponding salt of the acid to give unsaturated aromatic acid