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Q.

In which of the following reactions benzene will not formed?

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a

$n - h e x a n e \to_{300^{0} C}^{A n h y d r o u s A l C l_{3} \cdot H C l}$

b

$C_{6} H_{5} O H \overset{Z n d u s t}{\to}$

c

$C_{6} H_{5} C O O N a \overset{N a O H + C a O}{\to}$

d

$C_{6} H_{5} N_{2}^{+} C l^{-} \underset{Δ}{\overset{H_{3} P O_{2}}{\to}}$

answer is D.

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Detailed Solution

$1) C_{6} H_{5} C O O N a \overset{N a O H + C a O}{\to} C_{6} H_{6}$

$2) C_{6} H_{5} O H \overset{Z n d u s t}{\to} C_{6} H_{6}$

$3) C_{6} H_{5} N_{2}^{+} C l^{-} \underset{Δ}{\overset{H_{3} P O_{2}}{\to}} C_{6} H_{6}$

4) Isomerization takes place

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