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Q.

In which of the following reactions does H2O2 act as a reducing agent?

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a

2HI+H2O22H2O+I2

b

H2SO3+H2O2H2SO4+H2O

c

2FeCl2+2HCl+H2O22FeCl3+2H2O

d

Cl2+H2O22HCl+O2

answer is B.

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Detailed Solution

The reactions in which H2O2 acts as a reducing agent is,

Cl2+H2O22HCl+O2

Both oxidizing and reducing  H2O2 to H2O2 are possible. Consequently, it can function as an oxidising  agent by itself by becoming reduced to H2O  and a reducing agent by becoming oxidised to O2 . As a result, it has the ability to operate as an oxidizing and reducing agent. The reaction is having follows

H21O2H22O+O20

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