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Q.

In which of the following set of molecules central atoms are sp3 hybridised?

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a

NH2,PCl3,CH3

b

NH4+,BF4,SF4

c

PCl3,BCl3,NCl3

d

SnCl2,I3+,I3

answer is C.

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Detailed Solution

SP3is the hybridization of NH2. Due to this, there will be six couples instead of five: two with hydrogen and two lone individuals. PCl3 is hybridised with sp3 The PCl- bonds are essentially created when the chlorine's single-occupied 3p orbitals and the  sp3  hybrid orbitals overlap. Each chlorine atom also contains three lone pairs. In total, there are 3 electron pairs, 3 bond pairs, and 1 single pair of electrons in PCl3 .
Since the carbon atom in the ion CH3+ is sp2 hybridised, the geometry surrounding it is triangular planar. The H-C-H bond angle in this instance is 120°.

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