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Q.

In which of the following solution will $AgBr$ has highest solubility?

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a

$10^{- 3} M NaBr$

b

$10^{- 3} M {NH}_{4} OH$

c

Pure water

d

$10^{- 3} M HBr$

answer is B.

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Detailed Solution

$AgBr$ will form soluble complex with ${NH}_{4} OH$ .

${Ag}^{+} + 2 {NH}_{3} ⟶ (Ag {({NH}_{3})}_{2}^{+})$ due to complex formation, solubility of $AgBr$ increases.

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