Q.

In which of the following species maximum atom lie in same plane?

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a

PCl5

b

XeF4

c

XeF2O2

d

AsH4+

answer is D.

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Detailed Solution

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Analysis of Options:

  1. XeF₂ (Option a):
    • Geometry: Linear
    • Atoms in the same plane: The two fluorine atoms and xenon atom lie on the same line, which is a plane.
    • Count of atoms in the same plane: 3.
  2. PCl₅ (Option b):
    • Geometry: Trigonal bipyramidal
    • Atoms in the same plane: In the trigonal bipyramidal structure, the three equatorial chlorine atoms lie in the same plane as phosphorus.
    • Count of atoms in the same plane: 4.
  3. AsH₄⁺ (Option c):
    • Geometry: Tetrahedral
    • Atoms in the same plane: In a tetrahedral geometry, no three atoms lie in the same plane.
    • Count of atoms in the same plane: 2 (at most, if you consider the projection).
  4. XeF₄ (Option d):
    • Geometry: Square planar
    • Atoms in the same plane: In a square planar geometry, the central xenon atom and all four fluorine atoms lie in the same plane.
    • Count of atoms in the same plane: 5.

Answer: d: XeF₄

  • In XeF₄, the maximum number of atoms (5) lie in the same plane due to its square planar geometry.
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