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Q.

In which pair, the stronger bond is found in the first species ? 
a) O2-,O2  b) N2,N2+ c) NO+,NO-

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a

a only

b

b only

c

a and c only

d

b and c only

answer is D.

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Detailed Solution

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Higher is the bond order, stronger is the bond formed.

O2- : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py2π*2pz1 B.O=10-72=1.5

O2(16e-) : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py1π*2pz1 B.O=10-62=2

N2(14e-) : σ1s2σ*1s2σ2s2σ*2s2π2py2π2pz2σ2px2 B.O=10-42=3

N2+(13e-) : σ1s2σ*1s2σ2s2σ*2s2π2py2π2pz2σ2px1 B.O=9-42=2.5

NO+(14e-) : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2 B.O=10-42=3

NO-(16e-) : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py1π*2pz1 B.O=10-62=2

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