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Q.

In which species does the central atom have one or more lone pairs of valence electrons?

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a

SO2

b

CO2

c

PCl4+

d

AlCl4

answer is D.

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Detailed Solution

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S is the primary element in the SO2 molecule, whereas O is its neighbour.
Bond pairings = other elements in the formula besides the primary element + 2
Number of lone pairs = 1/2 × (No. of the central atom's valence electrons - Total No. of bonds present between the central element and the surrounding elements) =1/2 × (6 - 4) = 1

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