Q.

In Zeisel’s method for the determination of methoxyl groups, a sample of 2.68 gm of a compound (A) gave 14.08 gm of AgI. If the molecular weight of compound (A) is 134. Find the number of (OCH3) group(s) in the compound (A).

(Given is Ag = 108, I =127) (Rounding to the nearest integer)

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answer is 3.

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Detailed Solution

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2.68 gm of (A) gives 14.08 gm of AgI 
134 gm of (A) gives  14.08x1342.68
=704gmofAgI =704235=molofAgI =3(OMe)groups

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