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Q.

In Zeisel’s method for the determination of methoxy groups a sample of 2.68g of a compound (A) gave 14.08g of AgI. If the molecular weight of compound (A) is 134. Then the number of (OCH3)  groups in the compound (A) is (round off nearest integer) (atomic weights of Ag=108, I=127, C=12, O=16, H=1) 

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answer is 3.

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Detailed Solution

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No. of moles of compound  A=2.68134=0.02
No. of moles of AgI =  14.08235=0.06
i.e. 1 mole of a gives 3 moles of AgI, i.e. three 0,  H3  groups are present 

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