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Q.

In B3N3H6 compound, the correct option is (State 'T' for True and 'F' for False):

(I) Three - bonds present in B3N3H6.
(II) It shows back bonding.
(III) It is non-polar compound with non polar bonds.
(IV) - bonding is also present.

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a

TTTF

b

TTTT

c

TTFF

d

FTTF

answer is A.

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Detailed Solution

Borazine has a molecular formula B3N3H6. It has three B and three N atoms present at alternate positions in a hexagonal ring. Each B and N atom has one hydrogen atom. 

The boron atom has one vacant 2pz orbital and N has one lone pair of electrons present in the 2pz orbital. There is back bonding that takes place between B and N atoms, this back bonding is also referred to as - bonding. As there are three B and three N atoms, hence there are three back bonding(- bonding)

There is an electronegativity difference between B and N, hence bond between B and N is polar while the compound is nonpolar because of has zero dipole moment. 

B and N have no d-orbitals, therefore - bonding is not possible.

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