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Q.

In CH3CCl3 (I), CHCl3 (II) and CH3Cl (III)  ln the normal tetrahedral bond angle is maintained. Also given cos 70.5=13Therefore dipole moments of the given compounds are: (given due to -I effect of Cl, the bond moment of H-C bond directed towards the H in CHCI3 )

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a

I=1.9D,II=1.7D,III=1.7D

b

I=1.9D,II=1.9D,III=1.7D

c

I=1.9D,II=1.1D,III=1.9D

d

I=1.9D,II=1.7D,III=1.9D

answer is D.

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Detailed Solution

In CCl4,μ=0 so consider

μCCl of 3Cl=μCCl of 1 Cl. Similarly, in case of 

Now,

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