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Q.

Incorrect statement among the following

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a

Acetyl peroxide is used as a free radical generating initiator in free radical mechanism

b

Ziegler-Natta catalyst is triethyl aluminium and titanium tetra chloride

c

In cation polymersation termination step is absent

d

Alkyl Lithium compounds are effective chain initiators

answer is A.

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Detailed Solution

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For example, Ethylene cation polymerization is a type of cationic polymerization that involves the use of a Lewis acid catalyst, such as aluminum chloride (AlCl3), to initiate the reaction. The general mechanism for ethylene cation polymerization can be described as follows:

  • Initiation: The Lewis acid catalyst, AlCl3, reacts with ethylene to form a carbocationic species:

                AlCl3 + C2H4 → AlCl2+ + CH3-CH2+Cl-

  • Propagation: The carbocationic species reacts with another ethylene molecule to form a new carbocationic species and a growing polymer chain:

                CH3-CH2+ + C2H4 → CH3CH2CH2+ + H2C=CH2

The process repeats, adding more ethylene monomers to the growing polymer chain.

  • Termination: The polymerization reaction stops when all of the monomer is consumed. Termination occurs when the carbocationic species reacts with a counterion, such as the chloride ion (Cl-), to form a neutral molecule:

                CH3-CH2+ + Cl- → CH3CH2Cl

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