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Q.

Incorrect statement among the following is;

I) LiAlH4 can reduce an amide into an amine without change in the number of carbon atoms

II) A primary amide can be reduced to a primary amine by Br2/KOH with the same number of carbons

III) A primary amide can be reduced to a primary amine by LiAlH4 with (n-1) carbon atoms

IV) Hoffmann's bromamide reaction is useful to prepare aniline from benzamide

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a

 III and IV

b

 II only

c

 I only

d

 II and III

answer is D.

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Detailed Solution

  • A primary amide cannot be reduced to a primary amine by Br2/KOH with the same number of carbons. A primary amide cannot be reduced to a primary amine by LiAlH4 with (n-1) carbon atoms. A primary amide can be reduced to a primary amine by LiAlH4 with n carbon atoms.
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