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Q.

Incorrect statement is

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a

2l+S2O82l2+2SO42 catalyst is Fe+3 and intermediate is Fe+2

b

Interstitial compounds are chemically reactive

c

Difference in metallic radii between two metals forming alloy must be lessthan 15%

d

V2O5 is amphoteric

answer is B.

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Detailed Solution

  •  S2O8-2+2I-2SO4-2+I2

Mechanism:

2Fe+3+2I-2Fe+2+I2 2Fe+2+S2O8-22Fe+3+2SO4-2

In the above reaction moles of  Fe+3 ions before the reaction and after the reaction remains same, hence Fe+3 ion acts as catalyst.

Fe+2 ion is formed as intermediate. (True)

  • Interstitial compounds are chemically inert, hence they are using as refractory materials.(False).
  • Difference between the atomic radii of alloy forming metals must be about 15% (True)
  • V2O3 and V2O4 are basic and V2O5 is amphoteric oxide(True)
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