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Q.

Incorrect statement is

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a

Cr2O7-2 is a strong oxidizing agent but not WO3 and MoO3

b

Cr+2 is a good reducing agent

c

ENi+2/Nio more negative than expected due to high hydration energy of Ni+2 ion

d

MnO3F does not exist

answer is D.

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Detailed Solution

  • stability order(Higher Ox.St) :Cr+3<Mo+3<W+3 Oxidising power order:           Cr+3>Mo+3>W+3

In transition elements from top to bottom higher oxidation state stability increases, hence oxidizing power decreases.

  • Cr+2 is a strong reducing agent, reduces H+ ions to hydrogen as it gets stable t2g3 configuration.  2Cr+2t2g4+2H+2Ct2g3r+3+H2
  • Due to high hydration energy of Ni+2 ion nickel SOP is very high, i.e., SRP is low (more negative)
  • Simple halides of Mn with  +7 state were  not found but MnO3F is known. So,4th statement incorrect.
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