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Q.

Increasing order of stability of the following carbocations

C+H3I ,C+D3II , C+T3III

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a

I < II < III

b

III < II < I

c

II < I < III

d

I < III < II

answer is A.

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Detailed Solution

As + IE increases,Stability increaesC+H3 < C+D3 <C+T3  Heavier isotope has more electron releasing power than the lower isotope

Order of +I Effect:

T > D >H

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